Here, we report the first such use of photoredox catalysis to promote While the ratio \(\frac{C_{A^{-}}}{C_{HA}}\) is always equal to 1, the ratio \(\frac{[A^{-}]}{[HA]}\) rockets away. Correspondence to eg. In the second stage, it emits a photon of energy and either returns to the ground state or jumps into an excited state. A general method for the direct deoxygenative cross-coupling of free alcohols must overcome several challenges, most notably the in situ cleavage of strong CO bonds3, but would allow access to the vast collection of commercially available, structurally diverse alcohols as coupling partners4. Dynamic kinetic cross-electrophile arylation of benzyl alcohols by nickel catalysis. A reducing sugar is a carbohydrate that is oxidized by a weak oxidizing agent (an oxidizing agent capable of oxidizing aldehydes but not alcohols, such as the Tollen’s reagent) in basic aqueous Soc. Nature Communications This is a list of cocaine analogues.A cocaine analogue is an (usually) artificial construct of a novel chemical compound from (often the starting point of natural) cocaine's molecular structure, with the result product sufficiently similar to cocaine to display similarity in, but alteration to, its chemical function. Reference; The following equation, which relates the pH of an aqueous solution of an acid to the acid dissociation constant of the acid, is known as the Henderson-Hasselbach equation. Aspertaichunol A (1), a polyketide with a novel scaffold, was isolated from the medicinal insect (Periplaneta americana)-derived endophytic Aspergillus taichungensis SMU01. No headers Constitutional or structural isomers are compounds with the same molecular formula but different structural formulas.. eg. Science 334, 11141117 (2011). Excelente para las prcticas de laboratorio. We can reach the target concentrations of acid and conjugate base by adding \(50\ mL\) of strong base at the same concentration \(0.9\ mol\ L^{-1}\) (neutralizing half the original acid). (Wiley & Sons, 2016).pdf. The 1H and 13C NMR chemical shifts are respectively 1.873 and 1.756 ppm and are 28.46 and 37.85 ppm. Choi, J. Gusev, D. G. Electronic and steric parameters of 76 N-heterocyclic carbenes in Ni(CO)3(NHC). In this case, we have [3.3.1]nonane since there is a third ring with one carbon atom, while [3.3.0]nonane indicated only two rings.. Bicyclic Compounds with Substituents. Police determined that, based on a purchase made earlier in the day, the couple had left their home in West Lafayette, Indiana, and headed north. 03 May 2022. To get the proton concentration, replaced every value of 0.9 with 0.09, then 0.009, and so on. This relationship is used to determine the \(pK_a\) of compounds experimentally. [33] They had met at a choir of which they were both members at in university. 26", "Japanese Nobel Prize Chemists Honored By Royal Society Of Chemistry", "Police: No foul play in death of wife of Purdue Nobel Prize winner found in Illinois", "Autopsy: Hypothermia, complicated by Parkinson's and hypertension killed professor's wife", "Ei-ichi Negishi, Nobel Prize Winner in Chemistry, Dies at 85", "Japanese Nobel laureate chemist Negishi dies at 85", https://en.wikipedia.org/w/index.php?title=Ei-ichi_Negishi&oldid=1119679746, Foreign associates of the National Academy of Sciences, Pages containing links to subscription-only content, Short description is different from Wikidata, Articles containing Japanese-language text, Nobelprize template using Wikidata property P8024, Creative Commons Attribution-ShareAlike License 3.0, Sir Edward Frankland Prize Lectureship (2000), 1996 A. R. Day Award (ACS Philadelphia Section award), 1998 American Chemical Society Award for Organometallic Chemistry, 19982000 Alexander von Humboldt Senior Researcher Award, 2007 Gold Medal of Charles University, Prague, Czech Republic, 2010 ACS Award for Creative Work in Synthetic Organic Chemistry, 2015 Fray International Sustainability Award, SIPS 2015, 196061 FulbrightSmithMundt Fellowship, 196263 Harrison Fellowship at University of Pennsylvania, 2000 Sir Edward Frankland Prize Lectureship, 2009 Invited Lectureship, 4th Mitsui International Catalysis Symposium (MICS-4), Kisarazu, Japan, 2011 Order of the Griffin, Purdue University, This page was last edited on 2 November 2022, at 21:13. The resulting approximation breaks down in sufficiently dilute solution, and is already quite noticeable far before reaching water self-dissociation issues. After looking at this first case, we shall investigate the effects of dilution by factors of 10. [3] He was 85 years old. Its structure was assigned on the basis of spectroscopic data and quantum chemical computational methods. The left- and right-wing fragments were assembled via the diastereoselective Mukaiyama aldol reaction catalyzed by a chiral hydrogen bond donor. Organic & Biomolecular Chemistry, 3(24), 4351. doi:10.1039/b511998g . Corbet, J.-P. & Mignani, G. Selected patented cross-coupling reaction technologies. Soc. The Ogle County Sheriff Department said there was no suspicion of foul play in Suzuki's death, although the cause of her death was not immediately released. Merck Center for Catalysis at Princeton University, Princeton, NJ, USA, You can also search for this author in Metal-catalysed cross-couplings are a mainstay of organic synthesis and are widely used for the formation of CC bonds, particularly in the production of unsaturated scaffolds1. The acid dissociation constant of \(HA\), \[\log_{10}[H_3O^+] = \log_{10} K_a + \log_{10} \dfrac{[HA]}{[A^-]}\]. 126, 27632767 (2004). In solid-state NMR spectroscopy, adamantane is a common standard for chemical shift referencing. Google Scholar. the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in No headers. The skeleton of 2 bore an unneeded carbon atom. 142, 72257234 (2020). Its fragmentation results in weaker signals as m/z = 93, 80, 79, 67, 41 and 39. Yuan, M., Song, Z., Badir, S. O., Molander, G. A. In the second stage, it emits a photon of energy and either returns to the ground state or jumps into an excited state. Alcohol adducts of N-heterocyclic carbenes: latent catalysts for the thermally-controlled living polymerization of cyclic esters. Soc. No headers. The authors declare no competing interests. Soc. On the nature of C(sp3)C(sp2) bond formation in nickel-catalyzed tertiary radical cross-couplings: a case study of Ni/photoredox catalytic cross-coupling of alkyl radicals and aryl halides. Chem. 125, 25462558 (2003). Serving as a homoenolate precursor, 1,2-substituted cyclopropanols can now be converted to the corresponding cyclopropylamines via ring opening, intermolecular condensation with amines, and cyclization to reform the three-membered ring. [44] A nitrogen-substituted drug amantadine can be prepared by reacting adamantane with bromine or nitric acid to give the bromide or nitroester at the 1-position. He spent most of his career at Purdue University in the United States, where he was the Herbert C. Brown Distinguished Professor and the director of the Negishi-Brown Institute. A reducing sugar is a carbohydrate that is oxidized by a weak oxidizing agent (an oxidizing agent capable of oxidizing aldehydes but not alcohols, such as the Tollens reagent) in basic aqueous solution. Let us consider the simple case of solutions of a weak monoprotic acid \(\ce{HA}\) with acid dissociation constant \(K_a\) where the concentration of acid and conjugate base are formally equal. 134, 61466159 (2012). Zhang, X. (: adamantane : ) 10 C 10 H 16 136.23 270 C CAS [281-23-2] "adamas" A short time later, Suzuki's body was found at the Orchard Hills Landfill in Davis Junction, along with the couple's car. A. J. In NMR spectroscopy, J-coupling contains information about Accessibility StatementFor more information contact us atinfo@libretexts.orgor check out our status page at https://status.libretexts.org. [35], Negishi died in Indianapolis, Indiana, on June 6, 2021. 1988 - Organic Chemistry Laboratory Survival Manual. [4] He was awarded the 2010 Nobel Prize in Chemistry "for palladium catalyzed cross couplings in organic synthesis" jointly with Richard F. Heck and Akira Suzuki. Download Free PDF View PDF. Fanny Ainunnisa. The adamantane cation can be produced by treating 1-fluoro-adamantane with SbF5. K). Additions of radicals generated through photoredox catalysis to carboncarbon -bonds are well-established; however, this approach has yet to be applied to the functionalization of carboncarbon -bonds. Also called -olefins, terminal alkenes are more useful. Soc. prepared this manuscript. The presence of substituents in a bicyclic compound doesnt affect the main rule for numbering which is to start it from one of the bridgehead carbon atoms and move in the direction of the larger ring towards Herrmann, J. M. & Knig, B. Reductive deoxygenation of alcohols: catalytic methods beyond BartonMcCombie deoxygenation. [6][3] Following the transfer of his father who worked at the South Manchuria Railway in 1936, he moved to Harbin, and lived eight years there. This is a weak monoprotic acid, so the initial solution must have \([H^+] < 9 \times 10^{-4}\ mol\ L^{-1}\) and thus \(pH\). Its structure was assigned on the basis of spectroscopic data and quantum chemical computational methods. We report herein a metallaphotoredox-based cross-coupling platform in which free alcohols are activated in situ by N-heterocyclic carbene salts for carboncarbon bond formation with aryl halide coupling partners. ); a Crohns and Colitis Foundation of America fellowship (S.Y. Clearly it's impossible to add any amount of strong base to this acid and get a buffer solution with \(pH=3\)! [7] In 1943, when he was nine, the Negishi family moved to Incheon, and a year later to Kyongsong Prefecture (now Seoul), both in Japanese-occupied Korea. 106, 26512710 (2006). Chemistry of Carbon Compounds. \(\ce{KOH}\)). Hasil scan Perry's Chemical Engineers' Handbook. Macromolecules 39, 56175628 (2006). It's an irony of modern organic chemistry that the simplest-looking carbon-carbon bonds are often the hardest to make. Since the charge of cation formed in the mass spectrometer is almost always +1, the mass-to-charge ratio of a cation is usually equal to the mass of the cation. & Cossy, J. Cobalt-catalyzed cross-coupling of 3- and 4-iodopiperidines with grignard reagents. Chem. Angew. Inorganic Chemistry Housecroft. Gonnard, L., Gurinot, A. Therefore, butane and isobutane are constitutional isomers. Am. We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. Two general types of monoalkenes are distinguished: terminal and internal. For a 0/90 geometry, quantum yield standards are typically fluorescent organic dyes of known quantum yield under specified experimental conditions (pH, solvent, and temperature) [66].As discussed in Section 7.7.4, to avoid quenching effects, all solutions should be degassed, and solvents and cuvettes should be of spectral grade and checked for spurious emission. No headers. The initial stages of an enantioselective synthesis of (R)-1-hydroxy-7-methoxy-1,2,3,4-tetrahydronaphthalene-1-carboxylic acid required J. [10][3], After obtaining his Ph.D., Negishi decided to become an academic researcher. In particular, a robust and general method for the direct deoxygenative coupling of alcohols would have major implications for the field of organic synthesis. The data supporting the findings of this study are available within the paper and itsSupplementary Information. The Henderson-Hasselbach equation is derived from the definition of the acid dissociation constant as follows. -Turns are one of the most common structural motifs in proteins and change the direction of the peptide backbone by nearly 180, allowing the peptide chain to fold back onto itself. The cover art illustrates the first intermolecular electrophilic trapping of metal ketone homoenolates. These encompass acyclic, cyclic, caged, bridgehead, fluoroalkyl, and benzylic acids, which were transformed to the corresponding Bpin esters smoothly. At about 5 a.m. the next day, officers in Ogle County, Illinois, received a call to check on the welfare of an elderly man who was walking on a rural road south of Rockford. Fluorination of adamantane with gaseous fluorine has also been reported. The left- and right-wing fragments were assembled via the diastereoselective Mukaiyama aldol reaction catalyzed by a chiral hydrogen bond donor. In organic chemistry, an alkene is a hydrocarbon containing a carboncarbon double bond.. Alkene is often used as synonym of olefin, that is, any hydrocarbon containing one or more double bonds. [15] He returned to Purdue University as a full professor in the same year. a Shanghai Institute of Organic Chemistry, Zhejiang Medicine Co., and Pharmaron postdoctoral fellowship (J.W. The presence of substituents in a bicyclic compound doesnt affect the main rule for numbering which is to start it from one of the bridgehead carbon atoms and move in the direction of the larger ring towards Alejandra Salazar. 1988 - Organic Chemistry Laboratory Survival Manual. This can be done by titrating half of the weak acid with a strong monoprotic base (e.g. eg. Most reactions owe their efficiency to neighboring double bonds or oxygen and nitrogen atoms that linger in the products. 142, 1169111697 (2020). Soc. [27] Such optical activity was described in adamantane in 1969 with the four different substituents being hydrogen, bromine and methyl and carboxyl group. The 1 H-NMR spectra of 6 and 7 displayed two proton signals at the bridgehead carbons (H-1,5) in the range of 2.903.511.68 ppm. [3] They married the next year and together they had two daughters. Reference; The following equation, which relates the pH of an aqueous solution of an acid to the acid dissociation constant of the acid, is known as the Henderson-Hasselbach equation. Fanny Ainunnisa. \(V_A\) is the volume of the weak acid solution being titrated and \(C^o_A\) is its formal initial concentration (before mixing and reacting with the base), while \(V_B\) is a variable volume of strong base solution added with formal initial concentration \(C^o_B\) (before mixing and reacting with the acid). Peer review information Nature thanks the anonymous reviewer(s) for their contribution to the peer review of this work. The first adamantane derivative used as a drug was amantadine first (1967) as an antiviral drug against various strains of influenza[49] and then to treat Parkinson's disease. Within the scope of analogous compounds created from the structure of Chem. & Fu, G. C. Transition metalcatalyzed alkyl-alkyl bond formation: another dimension in cross-coupling chemistry. Independent of the level of dilution, so long as the concentration of acid and conjugate base remain equal, then according to the approximation, \(pH=pK_a=3\). 1 Aryl halide scope for deoxygenative arylation. Also called -olefins, terminal alkenes are more useful. Chiral Center, chiral atom, chirality center, or center of chirality is a tetrahedral atom in a molecule bearing four different ligands, with lone pairs, if any, treated as ligands. Chem. The dication of 1,3-didehydroadamantane was obtained in solutions of superacids. He was awarded the 2010 Nobel [2][3] He spent most of his career at Purdue University in the United States, where he was the Herbert C. Brown Distinguished Professor and the director of the Negishi-Brown Institute. It's an irony of modern organic chemistry that the simplest-looking carbon-carbon bonds are often the hardest to make. These encompass acyclic, cyclic, caged, bridgehead, fluoroalkyl, and benzylic acids, which were transformed to the corresponding Bpin esters smoothly. Dong, Z., MacMillan, D.W.C. [48], All medical applications known so far involve not pure adamantane, but its derivatives. Its stability is relatively high.[30][31]. ); a Crohns and Colitis Foundation of America fellowship (S.Y. In mass spectroscopy, the mass-to-charge ratio (symbols: m/z, m/e) of a cation is equal to the mass of the cation divided by its charge. Enantioselective total syntheses of ()-grayanotoxin III, (+)-principinol E, and ()-rhodomollein XX were accomplished based on a convergent strategy. No headers. The molecule is both rigid and virtually stress-free. Trnka, T. M. et al. ); a Crohns and Colitis Foundation of America fellowship (S.Y. N-Bromosuccinimide As A Reagent In Organic ChemistryIn a blatant plug for the Reagent Guide, each Friday I profile a different reagent that is commonly encountered in Org 1/ Org 2.. N-Bromosuccinimide Is A More Convenient Alternative To Bromine (Br 2). https://doi.org/10.1038/s41586-021-03920-6, DOI: https://doi.org/10.1038/s41586-021-03920-6. This can be performed simply by diluting both the initial weak acid and strong base concentrations by 10 (i.e., \(100\ mL\) of \(0.09\ mol\ L^{-1}\) \(\ce{HA}\) plus \(50\ mL\) of \(0.09\ mol\ L^{-1}\) \(\ce{KOH}\) result in a buffer with acid/conjugate base concentrations of \(0.03\ mol\ L^{-1}\), and so on). In November 1945, three months after World War II ended, they moved to Japan. [2], Elastic constants of adamantane were measured using large (centimeter-sized) single crystals and the ultrasonic echo technique. Inorganic Chemistry By GARY L. MIESSLER. Adamantane was recently identified as a key structural subunit in several synthetic cannabinoid designer drugs, namely AB-001 and SDB-001. a Shanghai Institute of Organic Chemistry, Zhejiang Medicine Co., and Pharmaron postdoctoral fellowship (J.W. Kochi, J. K. Chemistry of alkoxy radicals: cleavage reactions. 54, 64056416 (2011). Organic & Biomolecular Chemistry, 3(24), 4351. doi:10.1039/b511998g . 84, 11931197 (1962). If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate. In the first stage, the quantum system absorbs a photon of energy to assume a virtual state. Inorganic Chemistry Housecroft. & MacMillan, D. W. C. Alcohols as latent coupling fragments for metallaphotoredox catalysis: sp3 sp2 cross-coupling of oxalates with aryl halides. Internet Explorer). ADS 7, 39553959 (2017). Now, for the calculations. Download Free PDF View PDF. Kato, T., Matsuoka, S. & Suzuki, M. N-heterocyclic carbene-mediated redox condensation of alcohols. Later, fluorination was achieved starting from adamantane itself. J. Download Free PDF View PDF. Adamantane derivatives with different substituents at every nodal carbon sites are chiral. Notably, 1 possesses an uncommon tricyclo[6.2.0.02,6]decane motif and an unusual The LibreTexts libraries arePowered by NICE CXone Expertand are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. This was removed by singlet oxygenation, to give the ,-unsaturated aldehyde, that was decarbonylated with an Ir catalyst to 16. Metal-catalysed cross-couplings are a mainstay of organic synthesis and are widely used for the formation of CC bonds, particularly in the production of unsaturated scaffolds1. Replacing conventional carbon nucleophiles with electrophiles: nickel-catalyzed reductive alkylation of aryl bromides and chlorides. [37], The rate of bromination is accelerated upon addition of Lewis acids and is unchanged by irradiation or addition of free radicals. [14], Negishi began dating Sumire Suzuki in his freshman year and they announced their engagement to their parents in March 1958. Also called -olefins, terminal alkenes are more useful. Before any separations, he asked his student to evaluate crude reaction mixtures in order to minimize loss of any useful scientific information. Hasil scan Perry's Chemical Engineers' Handbook. The presence of the self-dissociation constant of water \(k_w\) shows that it is being taken into consideration. This results in \(pH=3.00288\), which is very close to the value predicted by the approximations made at the start (\(pH=pK_a+log\ 1=pK_a=3\)). Adamantane is an organic compound with a formula C 10 H 16 or, more descriptively, (CH) 4 (CH 2) 6.Adamantane molecules can be described as the fusion of three cyclohexane rings. Metal-catalysed cross-couplings are a mainstay of organic synthesis and are widely used for the formation of CC bonds, particularly in the production of unsaturated scaffolds1. The molecule is both rigid and virtually stress-free. 130, 1258612587 (2008). -Turns are one of the most common structural motifs in proteins and change the direction of the peptide backbone by nearly 180, allowing the peptide chain to fold back onto itself. and D.W.C.M. This is a list of cocaine analogues.A cocaine analogue is an (usually) artificial construct of a novel chemical compound from (often the starting point of natural) cocaine's molecular structure, with the result product sufficiently similar to cocaine to display similarity in, but alteration to, its chemical function. For more than one century, photochemical [2+2]-cycloadditions have been used by synthetic chemists to make cyclobutanes, four-membered carbon-based rings. Rev. Chemistry informer libraries: a chemoinformatics enabled approach to evaluate and advance synthetic methods. Bridgehead nitrogen heterocycles which contain the quinazoline moiety synthesis and cycloaddition of 1,2-dihydroquinazoline 3-oxides. Am. 55, 40404043 (2016). [citation needed]However, the International Union of The 1 H-NMR spectra of 6 and 7 displayed two proton signals at the bridgehead carbons (H-1,5) in the range of 2.903.511.68 ppm. { "(n_1)_Rule" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "-Elimination" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "-Ketoacid" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "-Ketoester" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "1-1_Link" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "1-4_Link" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "11-Diol" : "property get [Map 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MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkylation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkylborane : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_Carbanion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_Halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_sulfonate : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkynyl_carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkynyl_group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkynyl_halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkynyl_hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_Halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_Hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_Substitution : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alpha_Amino_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alpha_Anomer : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alpha_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alpha_Cleavage : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alpha_Hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Ambident_Nucleophile : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amide_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amine : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amine_Oxide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amino_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amino_Acid_Residue : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amino_Acid_Unit : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Ammonium_Ion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amphoteric : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anchimeric_Assistance : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Angle_Strain : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anhydride : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Annulene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anomeric_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anomeric_Center : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anomers : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Anti-Markovnikov_Addition" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Antiaromatic : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Antiaromatic_Annulene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Antiaromatic_Compound : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anticoplanar : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Antiparallel : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Antiperiplanar : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anti_Addition : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anti_Conformation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aprotic_Solvent : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Arene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Arenesulfonic_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Arenium_Ion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Amine : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Annulene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Compound : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Ether : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Hydrocarbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Carbanion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Ester : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryne : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Assisted_Homolysis : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Asymmetric_Carbon_Atom : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Autoxidation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Axial_Bond : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", A_Value : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Baeyer-Villiger_Oxidation" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Base : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Base_Peak : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Base_Strength : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beckmann_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Beer-Lambert_Law" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzene_Ring : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzilic_Acid_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzylic_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzylic_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzylic_Halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzylic_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzyl_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzyl_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzyne : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzyne_Mechanism : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Betaine : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beta_Amino_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beta_Anomer : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beta_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beta_Cleavage : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beta_Hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bicycloalkane : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Birch_Reduction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Boat_Conformation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bond_Angle : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bond_Axis : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bond_Dissociation_Energy : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Branched_Alkane : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bridge : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bridged_Bicycloalkane : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bridgehead_Carbon_Atom : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Brnsted-Lowry_Theory" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bromohydrin : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "C-Terminal" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Cahn-Ingold-Prelog_Convention" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbanion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbanion_Equivalent : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbene_Equivalent : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbenoid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbocation_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbocycle : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbohydrate : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbonyl_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbonyl_Compound : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbonyl_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbonyl_Oxygen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylate_Ion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Anhydride : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Derivative : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Ester : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Ester_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Salt : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Catalytic_Hydrogenation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Catalytic_Reduction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Center_of_Chirality : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", CFB : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chair_Conformation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chemically_Equivalent_Ligands : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chemical_Ionization : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chemical_Shift : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chemoselective : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chirality_Center : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chiral_Atom : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chiral_Center : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chiral_Molecule : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chlorofluorocarbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chlorohydrin : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chromate_Ester : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chromic_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", CIP_Convention : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Cis-Trans_Isomers" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Claisen_Condensation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Claisen_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Clemmensen_Reduction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Combustion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Concerted_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Condensation_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Configuration : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conformation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conformer : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conjugated_Diene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conjugated_Double_Bond : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conjugate_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conjugate_Addition : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conjugate_Base : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Constitutionally_Heterotopic : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Constitutional_Isomers : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Coordination_Number : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Cope_Elimination : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Cope_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Cope_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Coupling : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Coupling_Constant : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Coupling_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Crossed_Aldol_Condensation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Crossed_Aldol_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Crossed_Claisen_Condensation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Crosslink : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Crown_Ether : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.
